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Ferric hypophosphite, Fe(H2PO2)3

Ferric hypophosphite, Fe(H2PO2)3, is obtained as an insoluble white powder on dissolving freshly precipitated ferric hydroxide in dilute hypophosphorous acid in the cold, and allowing to evaporate. It decomposes on warming, yielding a mixture of ferrous and ferric hypo-phosphites; on warming with acids an evolution of hydrogen phosphide takes place.

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